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Design and synthesis of indole-substituted fullerene derivatives with different side groups for organic photovoltaic devices

Identifieur interne : 000295 ( Chine/Analysis ); précédent : 000294; suivant : 000296

Design and synthesis of indole-substituted fullerene derivatives with different side groups for organic photovoltaic devices

Auteurs : RBID : Pascal:13-0112125

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English descriptors

Abstract

A series of indole-substituted fulleropyrrolidine derivatives with different side groups on a pyrrolidine rings, including methyl (OIMC60P), benzyl (OIBC60P), 2,5-difluoroinebenzyl (OIB2FC60P), and 2,3,4,5,6-pentafluoroinebenzyl (OIB5FC60P), have been synthesized and used as electron acceptor in the active layer of polymer-fullerene solar cells to investigate the effect of various substitute groups on the electronic structures, morphologies, and device performances. Optical absorption, electrochemical properties and solubility of the fullerene derivatives have been explored and compared. The inverted photovoltaic devices with the configuration ITO/ZnO/Poly(3-hexylthiophene)(P3HT):[60]fullerene derivatives/MoO3/Ag have been prepared including the reference cell based on the P3HT: methyl [6,6]-phenyl-C61-butylate (PCBM) blend films. All the devices properties were measured in air without encapsulation. We also investigated the effect of the thermal annealing on the crystallinity and morphology of the active layer and the device performance. The device based on the blend film of P3HT and OIBC60P showed a power conversion efficiency of 2.46% under illumination by AM1.5G (100 mW/cm2) after the annealing treatment at 120 °C for 10 min in air.

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Pascal:13-0112125

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<div type="abstract" xml:lang="en">A series of indole-substituted fulleropyrrolidine derivatives with different side groups on a pyrrolidine rings, including methyl (OIMC60P), benzyl (OIBC60P), 2,5-difluoroinebenzyl (OIB2FC60P), and 2,3,4,5,6-pentafluoroinebenzyl (OIB5FC60P), have been synthesized and used as electron acceptor in the active layer of polymer-fullerene solar cells to investigate the effect of various substitute groups on the electronic structures, morphologies, and device performances. Optical absorption, electrochemical properties and solubility of the fullerene derivatives have been explored and compared. The inverted photovoltaic devices with the configuration ITO/ZnO/Poly(3-hexylthiophene)(P3HT):[60]fullerene derivatives/MoO
<sub>3</sub>
/Ag have been prepared including the reference cell based on the P3HT: methyl [6,6]-phenyl-C61-butylate (PCBM) blend films. All the devices properties were measured in air without encapsulation. We also investigated the effect of the thermal annealing on the crystallinity and morphology of the active layer and the device performance. The device based on the blend film of P3HT and OIBC60P showed a power conversion efficiency of 2.46% under illumination by AM1.5G (100 mW/cm
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<s0>Propriété électrochimique</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Electrochemical properties</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Propiedad electroquímica</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Solubilité</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Solubility</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Solubilidad</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Addition étain</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG">
<s0>Tin addition</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA">
<s0>Adición estaño</s0>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Encapsulation</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Encapsulation</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Encapsulación</s0>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Recuit thermique</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Thermal annealing</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA">
<s0>Recocido térmico</s0>
<s5>20</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE">
<s0>Cristallinité</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG">
<s0>Crystallinity</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA">
<s0>Cristalinidad</s0>
<s5>21</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE">
<s0>Dérivé de l'indole</s0>
<s5>22</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG">
<s0>Indole derivatives</s0>
<s5>22</s5>
</fC03>
<fC03 i1="22" i2="X" l="SPA">
<s0>Indol derivado</s0>
<s5>22</s5>
</fC03>
<fC03 i1="23" i2="3" l="FRE">
<s0>Composé du fullerène</s0>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="3" l="ENG">
<s0>Fullerene compounds</s0>
<s5>23</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE">
<s0>Fullerènes</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG">
<s0>Fullerenes</s0>
<s5>24</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>Oxyde d'indium</s0>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG">
<s0>Indium oxide</s0>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA">
<s0>Indio óxido</s0>
<s5>25</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE">
<s0>Oxyde de zinc</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="X" l="ENG">
<s0>Zinc oxide</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="X" l="SPA">
<s0>Zinc óxido</s0>
<s5>26</s5>
</fC03>
<fC03 i1="27" i2="X" l="FRE">
<s0>Thiophène dérivé polymère</s0>
<s2>NK</s2>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="ENG">
<s0>Thiophene derivative polymer</s0>
<s2>NK</s2>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="SPA">
<s0>Tiofeno derivado polímero</s0>
<s2>NK</s2>
<s5>27</s5>
</fC03>
<fC03 i1="28" i2="X" l="FRE">
<s0>Oxyde de molybdène</s0>
<s5>28</s5>
</fC03>
<fC03 i1="28" i2="X" l="ENG">
<s0>Molybdenum oxide</s0>
<s5>28</s5>
</fC03>
<fC03 i1="28" i2="X" l="SPA">
<s0>Molibdeno óxido</s0>
<s5>28</s5>
</fC03>
<fC03 i1="29" i2="X" l="FRE">
<s0>Acide butyrique</s0>
<s2>NK</s2>
<s5>29</s5>
</fC03>
<fC03 i1="29" i2="X" l="ENG">
<s0>Butyric acid</s0>
<s2>NK</s2>
<s5>29</s5>
</fC03>
<fC03 i1="29" i2="X" l="SPA">
<s0>Butírico ácido</s0>
<s2>NK</s2>
<s5>29</s5>
</fC03>
<fC03 i1="30" i2="X" l="FRE">
<s0>Ester</s0>
<s5>30</s5>
</fC03>
<fC03 i1="30" i2="X" l="ENG">
<s0>Ester</s0>
<s5>30</s5>
</fC03>
<fC03 i1="30" i2="X" l="SPA">
<s0>Ester</s0>
<s5>30</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE">
<s0>Couche mince</s0>
<s5>31</s5>
</fC03>
<fC03 i1="31" i2="X" l="ENG">
<s0>Thin film</s0>
<s5>31</s5>
</fC03>
<fC03 i1="31" i2="X" l="SPA">
<s0>Capa fina</s0>
<s5>31</s5>
</fC03>
<fC03 i1="32" i2="3" l="FRE">
<s0>Matériau dopé</s0>
<s5>46</s5>
</fC03>
<fC03 i1="32" i2="3" l="ENG">
<s0>Doped materials</s0>
<s5>46</s5>
</fC03>
<fC03 i1="33" i2="X" l="FRE">
<s0>Packaging électronique</s0>
<s5>47</s5>
</fC03>
<fC03 i1="33" i2="X" l="ENG">
<s0>Electronic packaging</s0>
<s5>47</s5>
</fC03>
<fC03 i1="33" i2="X" l="SPA">
<s0>Packaging electrónico</s0>
<s5>47</s5>
</fC03>
<fC03 i1="34" i2="X" l="FRE">
<s0>8105T</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="35" i2="X" l="FRE">
<s0>8535</s0>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="36" i2="X" l="FRE">
<s0>8460J</s0>
<s4>INC</s4>
<s5>58</s5>
</fC03>
<fC03 i1="37" i2="X" l="FRE">
<s0>7322</s0>
<s4>INC</s4>
<s5>59</s5>
</fC03>
<fC03 i1="38" i2="X" l="FRE">
<s0>ITO</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fC03 i1="39" i2="X" l="FRE">
<s0>ZnO</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fC03 i1="40" i2="X" l="FRE">
<s0>MoO3</s0>
<s4>INC</s4>
<s5>84</s5>
</fC03>
<fC03 i1="41" i2="X" l="FRE">
<s0>6865</s0>
<s4>INC</s4>
<s5>85</s5>
</fC03>
<fC03 i1="42" i2="X" l="FRE">
<s0>7840R</s0>
<s4>INC</s4>
<s5>86</s5>
</fC03>
<fC03 i1="43" i2="X" l="FRE">
<s0>7867</s0>
<s4>INC</s4>
<s5>87</s5>
</fC03>
<fN21>
<s1>084</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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   |wiki=   *** parameter Area/wikiCode missing *** 
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   |texte=   Design and synthesis of indole-substituted fullerene derivatives with different side groups for organic photovoltaic devices
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